I have tried it on my Laptops, Desktop and in Photoshop CC(2014) no problems. © ©
It probably does have something to do with software you have added. Perhaps the Alt key has been assigned to another function. Pretty stupid if it has. I used to use a Wacom Tablet but the software was a nightmare. That was a long time ago, never used it again.
Sony A7, A850, A77, A700 || Sony>> 70-300G, 28-75 f2.8 SAM, 16-80CZ, 50 f1.4, FE 28-70 OSS, FE 24-70CZ f4 OSS, LA-EA4 || Minolta>> 300 f4 G HS, 200 f2.8 G HS, 100 f2.8 (D) Macro, 50 f1.7, 28 f2.8, 28-135 f4-4.5, 70-210 f4, 500 f8 Reflex, TC x 1.4 HS, TC x 2 HS. || Sigma 21-35 f3.5-4.2. || Tamron SP 24-135.